Product ID:MARINE DIESEL FUEL, 33902
MSDS Date:10/15/1987
FSC:9150
NIIN:00N040292
MSDS Number: BSJDP

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-2252; 713-241-4819

Preparer: G A VAN GELDER

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

PUT IN CNTNRS & SEAL. FLUSH AREA W/WATER. DISP

WATERS THAT CAUSE SHEEN MUST BE RPRTD TO NATIONAL

A WEAK TO MOD CARCIN ACTIVITY. RPTD DERM APPLIC OF

ANIMALS HAS PRDCD EXTREMELY SEVERE IRRIT TO CORRO

WERE NOTED IN THESE STUDIES, INCLG CONGESTION,

DISTILLATE FUELS HAVE BEEN DEMONSTRATED TO CAUSE

CYTOGENETICS ASSAY & MUTAGENIC IN L5178Y MOUSE

VARIOUS TUMORS IN STUDIES WITH LABORATORY ANIMALS,

AS A POTENTIAL OCCUPATIONAL CARCINOGEN.

PROVIDE OXYGEN IF BRTHG IS DFCLT. GET MED

SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT

IF >2.0 ML PER KG HAS BEEN INGEST & VOMIT HAS NOT

VICTIMS HEAD BELOW HIPS TO PVNT ASPIRATION. IF

BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED

USE (ONLY) W/ADEQUATE VENTILATION. CNTNRS,

DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR

LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.

DIESEL FUELS; (SHELL MARINE DIESEL FUEL)

CAS: 68334-30-5

RTECS: HZ1800000

Fraction By Weight: 100%

FORMED UPON DECOMP.

ESPECIALLY HIVES. EARLY TO MODERATE CNS

& NAUSEA; IN EXTREME CASES, UNCON & DEATH MAY

& TISSUE DAMAGE A FEW HOURS FOLLOWING INJECTION.

BREATHING & CYANOSIS (BLUISH SKIN); IN SEVERE CASES

ASPIR PNEUM. RESULTS OF ANIMAL BIOASSAYS ON MIDDLE

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: PRACTICALLLY NONIRRIT TO EYES.
SKIN: MODERATELY IRRIT. PRLNGD/RPTD LIQ CONT CAN RSLT IN DEFAT &
DRYING OF SKIN WHICH MAY RSLT IN SEVERE IRRIT & DERM. MAY CAUSE
MILD SKIN SENSIT. RELEASE DURING H IGH PRESS USAGE MAY RSLT IN
INJECT OF OIL INTO SKIN CAUSING LOCAL NECROSIS. INHAL:VAPS/MISTS
MAY CAUSE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MILD IRRIT TO UPPER RESP TRACT. HIGH
CONC MAY RSLT IN CNS DEPRESS. INHAL OF HIGH LEVELS OF MIST MAY RSLT
IN CHEM PNEUM. INGEST: PROD MAY RSLT IN VOMIT; ASPIR(BRTHG)OF VOMIT
INTO LUNGS MUST B E AVOIDED AS EVEN SMLL QTYS MAY RSLT INASPIR
PNEUM. SKIN SENSIT(ALLERGY) MAY BE EVIDENCED BY RASHES, (ING 3)
Medical Cond Aggravated by Exposure:PRE-EXISTING AKIN & RESP DISORDERS
MAY BE AGGRAVATED BY EXPOS TO PROD. PRE-EXISTING SKIN/LUNG
ALLERGIES MAY INCREASE CHANCE OF DEVELOPING INCREASED ALLERGY
SYMPTOMS FROM EXPOSURE TO THIS PRODUCT.

First Aid:EYES: FLUSH EYES W/WATER FOR AT LEAST 15 MINS. GET MED ATTN.
SKIN: REMOVE CONTAMD CLTHG/SHOES & WIPE EXCESS FROM SKIN. FLUSH
SKIN W/WATER. FOLLOW BY WASHING W/SOAP & WATER. IF IRRIT OCCURS.
GET MED AT TN. DO NOT REUSE CLTHG UNTIL CLEANED. IF MATL IS
INJECTED UNDER SKIN. GET MED ATTN PROMPTLY TO PVNT SERIOUS DMG. DO
NOT WAIT FOR SYMPS TO DEVELOP. INHAL: REMOVE VICTIM TO FRESH AIR &
(ING 15)

Flash Point Method:PMCC
Flash Point:140F,60C
Extinguishing Media:USE WATER FOG,FOAM,DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNIT ON SURF OF WATER.
Fire Fighting Procedures:CAUTION. COMBUST. DO NOT ENTER CONFINED FIRE
SPACE W/OUT NIOSH/MSHA APPRVD POSITIVE PRESS SCBA & FULL PROT EQUIP
COOL FIRE EXPOS CNTNR W/WATER.(SUPP DATA)
Unusual Fire/Explosion Hazard:CNTNRS EXPOS TO INTENSE HEAT FROM FIRES
SHLD BE COOLED W/H*20 TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT IN
CNTNR RUPTURE.CNTNR AREAS EXPOS TO DIRECT(SUPP DATA)

Spill Release Procedures:CAUTION. COMBUST. LGE SPILLS: ELIM PTNTL
SOURCES OF IGNIT. WEAR APPROP RESP & OTHER PROT CLTHG. SHUT OFF
SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE & CNTN. REMOVE W/VACUUM
TRUCKS/PUMP TO STOR/SALV VES SELS. SOAK UP RESIDUE W/A SUITABLE
ABSORB (ING 23)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP LIQ & VAP AWAY FROM HEAT, SPARKS
& FLAME. SURFS THAT ARE SUFFICIENTLY HOT MAY IGNIT EVEN LIQ PROD IN
ABSENCE OF SPARKS/FLAME.
Other Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN OFF OTHER
SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE. VAPS MAY
ACCUM & TRAVEL TO IGNIT SOURCES DISTANT FROM HNDLG SITE: FLASH-FIRE
CAN RSLT. KEEP CN TNRS CLSD WHEN NOT IN USE. (ING 20)

Respiratory Protection:USE NIOSH/MSHA APPRVD RESP AS REQUIRED TO
PREVENT OVEREXPOSURE. IN ACCORDANCE W/29 CFR 1910.134, USE EITHER A
FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPO RS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APRV CHEMICAL WORKERS GOGGLES (FP N
Other Protective Equipment:WEAR CLOTHING AS REQUIRED TO MINIMIZE
CONTACT. AVOID PROLONGED & REPEATED CONTACT WITH SKIN.
Work Hygienic Practices:DO NOT REUSE CLTHG UNTIL CLEANED. WASH W/SOAP &
WATER BEFORE EATING, DRINKING, SMOKING/USING TOILET FACILITIES.(ING
22)
Supplemental Safety and Health
FIRE FIGHT PROC: LGE FIRES: ALSO COOL SURROUNDING EQUIP & STRUCTURES
W/WATER. EXPLO HAZ: FLAME CONT SHLD BE COOLED W/LGE QTYS OF WATER
AS NEEDED TO PVNT WEAKENING OF CNTNR STRUCTURE. HAZ DECOMP: & GAS
ES WILL EVOLVE WHEN THIS MATL UNDERGOESPYROLYSIS/COMBUST. CARBON
MONOXIDE & OTHER UNIDENTIFIED ORG CMPDS MAY BE (ING 2)

Boiling Pt:B.P. Text:325F,163C
Vapor Pres:<0.3 PSI
Vapor Density:>1
Spec Gravity:0.8654 (H*20=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOW LIQUID; STRONG HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT & FLAME.
Hazardous Decomposition Products:THERM DECOMP PRODS ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. A COMPLEX MIX OF AIRBORNE SOLID, LIQ,
PARTICULATES(SUPP DATA)

Waste Disposal Methods:PLACE IN NON-LEAKING CNTNRS & SEAL TIGHTLY FOR
PROPER DISPOSAL . DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS. HAZARDOUS WASTE #D001.

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